ALL
COMPRESSION WORK IS CONVERTED INTO HEAT AND IS LOST TO THE SURROUNDINGS
The obvious
implication of this statement, which you will find paraphrased by every
textbook writer quoted below, is that the source of compressed
air's ability to do work is the heat that was imparted to it by the sun.
This concept is of such importance that I will not attempt here
to paraphrase it once again; I will reprint the relevant sections of
ordinary compressed air textbooks and thermodynamics textbooks, and you
can judge for yourself.
Keep in mind that the
U.S. Patent Office gives patents to designers of self-fueling air
engines all the time. The patent office will not grant patents for
perpetual motion machines that have no energy source, and although
neither the patent office nor the patentees are forthcoming with the
energy source that make these machines patentable, when you see how many
of these patents exist, you must know that something is up. But I have
no secret to protect and no patent to hoard for myself, so here's the
documentation proving the Solar-Pneumatic Connection.
Documentation From Engineering Texts Showing That All
Compression Work Is Lost As Heat
"In the following articles it will be shown:
a. That the work of compression is all converted into heat.
b. That, after all the heat of compression has been abstracted,
there still remains in the compressed air a certain amount of energy
for doing useful work.
c. That this is due to the energy residing in the air before
compression."
(Simons, 1921; see last entry for full quote)
CROFT
In compressing the gas ...All
of this work (assuming a frictionless piston and no loss of heat) is
converted into heat in the compressed gas. Thereby the temperature of
the gas is increased. When the gas is permitted to expand, it does work
.... Its heat content and temperature are thereby decreased accordingly.
(Practical Heat, Terrell Croft, New York:
McGraw-Hill, 1923, p. 189.)
WIGHTMAN
Phenomena of
Compression.
Thermodynamics is the science of the relation between heat and
energy. It is based on two fundamental laws, only the first of which has
a bearing on the discussion of compressed air.
The First Law of Thermodynamics states that where heat is converted
into mechanical energy, or mechanical energy is converted into
heat, the quantity of heat is exactly equivalent to the amount of
mechanical energy.
This law demands that when work is done upon a volume of air in
compressing it from a lower to a higher pressure, a quantity of
heat must be developed exactly equivalent to the energy expended in
compression.
In other words, when a volume of air is compressed to a higher pressure,
all the work done upon that air volume is converted into heat; and that
heat acts to increase the temperature of the air volume, whether the
process of compression be slow or fast.
(Compressed
Air, Lucius Wightman, Chicago: American Technical Society, 1914, p.
6.)
SHONE
Availability
By the First Law of Thermodynamics and the principle of the
Conservation of Energy, a complete accounting can be made of all
relevant forms of energy entering, leaving, or contained in the
compressed air....
However, the First Law, being simply an energy balance,
provides little insight into the nature of the energy. For example, it
takes no account of the capacity of energy to do useful work or of the
inevitable dissipation, or degradation, of energy that accompanies all
real processes. For this the Second Law of Thermodynamics is required.
The Second Law has an undeservedly poor reputation, mainly
because of its apparent abstractions and its seeming irrelevance to
practical problem solving. By combining the concepts of the First and
Second Laws in a practical manner, energy may be classed as "available",
"unavailable" or "degraded". Basic to this classification is the concept
that the purpose of energy is to do useful work. Energy that is capable
of doing work is "available," that which cannot be employed for work is
"unavailable" and the available energy that is eroded by friction or
other dissipative processes is "degraded."
The work potential of compressed air is related to its
initial and final states. For example, an air receiver charged to a high
pressure clearly can provide more work if the air is expanded in a tool
and exhausted to atmosphere than if it were exhausted at a higher
pressure. It is equally clear that the work potential will be reduced if
there is a pressure drop in the piping between the receiver and the
tool.
Moreover, there is no doubt that the work potential will be
wasted entirely if the air is allowed to expand directly to atmosphere.
The
availability of compressed air
One of the sometimes puzzling aspects of compressed air,
which is not explained by the First Law, is that in most cases the
compressed air arriving at the tool contains no more energy than the
atmospheric air.... for an isothermal (constant temperature) process the
energy possessed by the air is unchanged .... The heat equivalent of the
input work is removed by cooling. It might appear therefore that
compressed air has been obtained with no net expenditure of energy and
that the eventual work is "free." This is manifestly incorrect, but it
is a fact that in compressed air installations heat is removed from the
air by cylinder jacket or internal cooling and by intercoolers,
aftercoolers and by heat transfers from surfaces. The result is that
shortly after compression storage and treatment, the compressed air has
the same temperature as at the inlet to the compressor.
(The South African Mechanical Engineer, vol.
35, August 1985, "A different view of compressed air," Dick Shone.)
UNWIN
Case of Isothermal Compression.—It will
be shown presently that the most economical compressor mechanically
would be one in which heat is abstracted during compression, so that the
compression is isothermal. In that case the effective work is...exactly
equal to the absolute work of compression ...But the heat abstracted
during compression is equal to the same quantity. Hence the curious
result is arrived at that in the most economical compression, the
effective work of compression is entirely abstracted as heat and wasted.
All the compression does is to put the air in a condition to do work in
a motor at the expense of its intrinsic energy. In that way there is
obtained an amount of work nearly equal to the work done in compression.
But the work in the motor is not strictly the restoration of the energy
expended in the compressor, but energy borrowed from the air....
(On
the Development and Transmission of Power from Central Stations,
William Cawthorne Unwin, London: Longmans, Green. 1894.)
FELLER
Important Fundamentals.—We know
that work is a force overcoming resistance and is measured in
foot-pounds. Energy, which exists in a number of forms, is the capacity
to do work and can also be measured in foot-pounds. Heat, measured in
BTU, is one form of energy. Power is the rate of doing work, the unit
being the horsepower, or 33,000 ft-lb per min. Temperature is an
indication of the direction in which heat will flow if it has the
opportunity to do so. The internal energy of air depends on its
temperature.
Work done in compressing air increases
the air's internal energy and raises its temperature. As the
compressor cylinder and piping are heat conductors, the whole of this heat soon
dissipates to surrounding bodies and the air's internal energy gradually
returns to its original value as the temperature falls to initial value.
Although 1 lb of air at 1,000 psi and
atmospheric temperature has no more internal energy than 1 lb at
atmospheric pressure and temperature, still the energy contained in the
air under pressure is available for use because this air can expand,
suffer a loss of pressure and
temperature, and give up a portion of its internal
energy. The greater the fall of pressure during expansion, the greater
the fall in temperature and the greater the amount of internal energy
available for use. The energy used in compressing air is not actually
stored up in the air unless the heat of compression is retained. A
portable compressor without cooling facilities furnishing air for
immediate use approaches this condition. This internal energy depends on
the temperature alone, and the energy that may be available for use
depends on the fall of pressure and drop in temperature permissible.
(Air
Compressors, Eugene W. F. Feller, New York: McGraw-Hill,
1944, p. 400-401.)
GRAHAM
It should be noted that the heat of
compression, as already explained, represents work done upon the air for
which there is usually no equivalent obtained, since the heat is all
lost by radiation, before the air is used.
(Audel's
Handy Book of Practical Electricity, Frank D. Graham, New York:
Audel, 1942, p. 5607.)
BARNARD/ELLENWOOD/HIRSHFELD
It is interesting to note that, from the
viewpoint of the conservation of energy, isothermal operation is not as
advantageous as adiabatic. The object of using the air expansively is to
utilize some of the internal energy of the working substance which
enters the engine. If the expansion is isothermal no work can be done at
the expense of such energy; on the contrary, heat equivalent in quantity
to the work done during the expansion period must be supplied from an
external source. With an adiabatic expansion, however, all of the work
done during such an expansion will be at the expense of the internal
energy of the gas.
The apparent discrepancy between these
two cases is due to the fact that during the isothermal expansion it is
assumed that the required amount of heat is supplied from the
atmosphere, and that it costs nothing, and may, therefore, be freely
used without decreasing the commercial efficiency of the process.
(Heat-Power
Engineering, William N. Barnard, Frank O. Ellenwood, Clarence F.
Hirshfeld, 3rd ed., New York: Wiley, 1926, p148.)
CHODZKO
There is nothing abnormal to an
efficiency greater than 1, when reheating is used; this will occur
(regardless of pipe and other friction) whenever the temperature of
reheating is higher than the temperature of compression.
(Modern
Machinery, January 1899, "The Two-Pipe System of Air Compression",
A. E. Chodzko, p. 11)
WRANGHAM
In isothermal compression there is no
gain of internal energy, or in pressure energy, since the
temperature remains constant…therefore by the Conservation Law, the
entire work of compression is discharged to the cooling water.
On these considerations it would appear
useless to compress a gas; actually, however, the increased pressure of
the gas enables it to expand to a lower pressure…
(The
Theory and Practice of Heat Engines, Digby Alfred Wrangham, The
Cambridge
University Press, p. 88)
SIMONS
Effect Of Loss Of Heat, Generated During Compression,
On The Ultimate Useful Energy Residing In A Given Quantity Of Compressed
Air
By an accepted law of thermodynamics,
work and heat are mutually convertible at the ratio of about 778 ft.-lb.
of work for every B.T.U.
In Article 41a it was stated that the
work expended in compressing air is all converted into heat. According
to the law quoted, we should expect the compressed, and therefore
heated, air to be capable of performing useful work, equal to the amount
expended in compressing it. Neglecting friction in the air engine, this
would actually be the case, if the compressed air could be used
immediately after compression and before it has lost any of its heat.
If, on the other hand, the compressed air
be allowed to cool down to the temperature which it possessed before
compression, as happens in all compressed air installations, it would
seem logical, by applying the same law quoted above, to reason as
follows:
Since the work of compression is all
converted into heat, the ability for doing useful work must have
disappeared after all this heat has been abstracted.
In the following articles it will be
shown:
a. That the work of compression is all
converted into heat.
b. That, after all the heat of
compression has been abstracted, there still remains in the compressed
air a certain amount of energy for doing useful work.
c. That this is due to the energy
residing in the air before compression.
(Compressed Air, Theodore Simons, 2nd ed., New York:
McGraw-Hill, 1921, p. 113-123)